33

As

Arsenic

74.9215956

Basic Information

Name

Arsenic

Atomic Number

33

Allotropes

Yellow Arsenic, Black Arsenic, Gray Arsenic

Appearance

Metallic gray

Refractive Index

1.001552

Phase At STP

Solid

Spectrum Image

Spectrum image of Arsenic

Source

Wikipedia

Bohr Model

Static

A 2D model of Arsenic

Interactive

Descriptive Numbers

CAS Number

7440-38-2

CID Number

{CID5359596, CID5359596, CID139279}

DOT Number

1558

RTECS Number

RTECSCG0525000

Mendeleev Number

95

Pettifor Number

89

Space Group Number

166

Glawe Number

90

Mass

Atomic Mass

74.9215956 Da

Uncertainty

0.000006

Periodic Position

X Position

15

Y Position

4

Period

4

Group

15

Classification

Block

p

Category

Metalloid

Geochemical

Semi-Volatile

Goldschmidt

Chalcophilic

Electrical Type

Conductive

Abundance

Urban Soil

0.0159 mg/kg

Seawater

3.7e-9 kg/L

Earth Crust

0.0000018 g

Human Body

0.000005 %

Solar System

0.0000066 mole ratio to silicon

Meteorites

0.00018 %

Color

Jmol

#BD80E3

Molcas Gv

#BD80E3

CPK

#FF1493

Atomic Radius

Empirical

115

Calculated

114

Van Der Waals

185

Bonding

185

Batsanov

205

Rahm

231

Dreiding

415

Uff

423

Mm3

236

Alvarez

188

Bragg

126

Covalent (Single Bound)

119

Covalent (Triple Bound)

106

Covalent (Cordero)

119

Covalent (Pyykko)

121

Covalent (Pyykko Double)

114

Covalent (Pyykko Triple)

106

Mendeleev

121

C12

148

Temperature

Melting/Freeze (WEL)

1090 °K

Melting/Freeze (CRC)

1090 °K

Melting/Freeze (LNG)

1090 °K

Boiling/Density (WEL)

887 °K

Boiling/Density (CRC)

876 °K

Boiling/Density (LNG)

888 °K

Boiling/Density (Zhang)

886 °K

Density

STP

5.727 kg/cm³

Solid (WEL)

5727 kg/cm³

Solid (CRC)

5750 kg/cm³

Solid (LNG)

5727 kg/cm³

Liquid (CR2)

5220 kg/cm³

Heat

Molar Volume

12.95 cm³/mol

Atomic Volume

13.1 cm³

Heat Of Fusion CRC

24.44 kJ/mol

Heat Of Fusion LNG

24.44 kJ/mol

Heat Of Fusion WEL

27.7 kJ/mol

Evaporation USE

32.4 kJ/mol

Evaporation WEL

32.4 kJ/mol

Evaporation Zhang

32.4 kJ/mol

Molar Heat

24.64 J/molK

Heat Capacity USE

0.328 J/gK

Heat Capacity CRC

24.64 J/gK

Heat Capacity LNG

24.64 J/gK

Heat Capacity WEL

24.6 J/gK

Adiabatic Index

N/A

Electrical Resistance

293k

333 nΩm

Magnetic Properties

Order

Diamagnetic

Susceptibility

-3.9e-9 m3/kg

Elasticity

Bulk Modulus

22 GPa

Youngs Modulus

8 GPa

Hardness

Mohs

3.5

Brinell

1440

Etymology

Description

It is a semi-metal element found in group 15. It has three allotropes: yellow, black and grey. It reacts with halogens, concentrated oxidizing acids and hot alkalis. Albertus Magnus is thought to be the first to isolate the element in 1250.

Language Of Origin

Syriac/Persian through Greek, Latin, Old French and Medieval English

Origin Of Word

From the English word (arsenicum in Latin)

Meaning

orpiment, zırnık

Symbol Origin

Hynanka of males

Etymological Description

Originally from the Greek word arsenikon, meaning "yellow zirnik", taken from Syriac (al-zarniqa) and Persian (zarnik). Arsenikon is related to the Greek arsenikos, meaning "masculine" or "strong". These words evolved into Latin arsenicum and Old French arsenic, which is the source of today's English word arsenic.

Discovery & Isolation

Observed/Predicted By

Middle Eastern alchemists

Observed/Discovery Year

before 815 AD

Isolated Sample By

Middle East

Isolated Sample Year

before 815 AD

Production & Use

Sources

It is found in mispixel (arsenopyrite).

Uses

Many of its compounds are fatally toxic. It is used as a herbicide and rat poison. It conducts electricity. It is used in semiconductors. Some of its compounds, known as arsenite, are used in making paint, wallpaper and ceramics.

Radioactivity

Half Life

Stable

Lifetime

Stable

Neutron Mass Absorption

0.002

Neutron Cross Section

4.3

Electron Affinity

Electron Affinity (eV)

0.804

Electron Affinity (kJ/mol)

77.65

Electron Affinity (pauling)

2.18

Electron Affinity (allen)

13.08

Electron Affinity (ghosh)

0.2068208

Dipole Polarity

Accepted

30

Uncertainty

1

C6 GB

260

C6 Coefficient

246

Lattice

Constant Internal Default Radius

4.13

Constant

375.98, 375.98, 1054.75

Strucutre

RHL

Angles

π/2, π/2, 2 π/3

Electron & Quantum

Oxidation States

−3,−2,−1,0,1,2,3,4,5

Electron Configuration

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3

Quantum Number

4h/a

Electron Configuration Semantic

pattern 3d10 4c2 chpz

Shells-0

2

Shells-1

8

Shells-2

18

Shells-3

5

Ionization Energies-0

947

Ionization Energies-1

1798

Ionization Energies-2

2735

Ionization Energies-3

4837

Ionization Energies-4

6043

Ionization Energies-5

12310

List of Compounds

1-10 of 97 compounds

FormulaNames
As

black arsenic

arsenic black

black amorphous arsenic

gray arsenic

arsenic gray

crystalline rhombohedral arsenic

metallic arsenic

As4

yellow arsenic

arsenic tetramer

arsenic yellow

crystalline cubic arsenic

non-metallic arsenic

tetraarsenic

AlAs

aluminum arsenide

alumanylidynearsane

aluminium arsenide

aluminum monoarsenide

AsBr3arsenic tribromide

arsenic bromide

arsenic(III) bromide

arsenous bromide

AsCl3arsenic trichloride

arsenic butter

arsenic chloride

arsenic(III) chloride

arsenious chloride

arsenous chloride

butter of arsenic

fuming liquid arsenic

trichloroarsane

trichloroarsine

AsF3arsenic trifluoridearsenic fluoride

arsenic(III) fluoride

arsenous fluoride

trifluoroarsine

AsF5arsenic pentafluoride

arsenic pentfluoride

arsenic(V) fluoride

arsorane, pentafluoro-

pentafluoridoarsenic

AsFe

iron arsenide

iron monoarsenide

GaAsgallium arsenide

gallanylidynearsane

gallium monoarsenide

AsH3arsine

arsenic hydride

arsenic trihydride

arsenous hydride

hydrogen arsenide

...


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