81

Tl

Thallium

204.38

Basic Information

Name

Thallium

Atomic Number

81

Appearance

Silvery white

Phase At STP

Solid

Spectrum Image

Spectrum image of Thallium

Source

Wikipedia

Bohr Model

Static

A 2D model of Thallium

Interactive

Descriptive Numbers

CAS Number

7440-28-0

CID Number

CID5359464

DOT Number

1707

RTECS Number

RTECSXG3425000

Mendeleev Number

85

Pettifor Number

78

Space Group Number

194

Glawe Number

81

Mass

Atomic Mass

204.38 Da

Periodic Position

X Position

13

Y Position

6

Period

6

Group

13

Classification

Block

p

Category

Post Transition Metal

Goldschmidt

Chalcophilic

Electrical Type

Conductive

Abundance

Urban Soil

0.0011 mg/kg

Seawater

1.9e-11 kg/L

Sun

2e-7 mole ratio to silicon

Earth Crust

8.5e-7 g

Solar System

1.9e-7 mole ratio to silicon

Meteorites

0.0000079 %

Color

Jmol

#A6544D

Molcas Gv

#A6544D

CPK

#FF1493

Atomic Radius

Empirical

190

Calculated

156

Van Der Waals

196

Bonding

196

Batsanov

220

Rahm

242

Uff

434.7

Mm3

259

Alvarez

247

Bragg

190

Covalent (Single Bound)

148

Covalent (Triple Bound)

150

Covalent (Cordero)

145

Covalent (Pyykko)

144

Covalent (Pyykko Double)

142

Covalent (Pyykko Triple)

150

Mendeleev

144

C12

160

Metallic

170

Temperature

Melting/Freeze (USE)

577 °K

Melting/Freeze (WEL)

577 °K

Melting/Freeze (CRC)

577 °K

Melting/Freeze (LNG)

576.5 °K

Boiling/Density (USE)

1746 °K

Boiling/Density (WEL)

1746 °K

Boiling/Density (CRC)

1746 °K

Boiling/Density (LNG)

1730 °K

Boiling/Density (Zhang)

1733 °K

Superconducting Point

2.38 °K

Density

STP

11.85 kg/cm³

Solid (WEL)

11850 kg/cm³

Solid (CRC)

11800 kg/cm³

Solid (LNG)

11850 kg/cm³

Liquid (CR2)

11220 kg/cm³

Heat

Molar Volume

17.22 cm³/mol

Atomic Volume

17.2 cm³

Heat Of Fusion USE

4.31 kJ/mol

Heat Of Fusion CRC

4.14 kJ/mol

Heat Of Fusion LNG

4.14 kJ/mol

Heat Of Fusion WEL

4.2 kJ/mol

Evaporation USE

162.4 kJ/mol

Evaporation LNG

165 kJ/mol

Evaporation WEL

165 kJ/mol

Evaporation Zhang

162 kJ/mol

Molar Heat

26.32 J/molK

Heat Capacity USE

0.128 J/gK

Heat Capacity CRC

26.32 J/gK

Heat Capacity LNG

26.32 J/gK

Heat Capacity WEL

26.3 J/gK

Thermal Conductivity

46.1 W/m*K

Thermal Expansion

0.0000299 1/K

Adiabatic Index

N/A

Speed of Sound

Extensional

818 m/s

Electrical Resistance

273k

150 nΩm

293k

180 nΩm

Magnetic Properties

Order

Diamagnetic

Susceptibility

-3e-9 m3/kg

Elasticity

Shear Modulus

2.8 GPa

Bulk Modulus

43 GPa

Poisson Ratio

0.45 ν

Youngs Modulus

8 GPa

Hardness

Mohs

1.2

Brinell

26.5–44.7

Etymology

Description

Unreacted, pure thallium has a silvery-white metallic luster. When it reacts with air, it turns bluish-gray and looks like lead. It has an extremely malleable structure and can be cut with a knife. It has two stable isotopes and four radioisotopes. TI-204 is the most stable with a half-life of 3.78 years. Thallium sulfate has been used as a rodenticide. The conductivity of thallium sulfide changes with exposure to infrared light. That's why it is used in infrared detectors. It was discovered by Sir William Crookes with the help of spectroscopy. Its name comes from the Greek word thallos, meaning "green branch". Thallium and its compounds are poisonous and can cause cancer.

Language Of Origin

Greek

Origin Of Word

From the Greek word thallos, meaning "green branch" or "green shoot"

Meaning

green shoot/twig

Symbol Origin

descriptive

Etymological Description

It comes from the Greek word thallos, meaning "green shoot (branch)". It emits light green spectrum lines.

Discovery & Isolation

Observed/Predicted By

W. Crookes

Observed/Discovery Year

1861

Discovery Location

England

Isolated Sample By

C.-A. Lamy

Isolated Sample Year

1862

Production & Use

Sources

Iron is found in pyrites. Croquesite, hutehinsot and lorandite are also encountered. Most of it is obtained from by-products of lead and zinc refining.

Uses

Its compounds are used in mouse and ant poisons. It is also used to detect infrared radiation.

Radioactivity

Half Life

Stable

Lifetime

Stable

Neutron Mass Absorption

0.0006

Neutron Cross Section

3.4

Electron Affinity

Electron Affinity (eV)

0.377

Electron Affinity (kJ/mol)

36.4

Electron Affinity (pauling)

1.62

Electron Affinity (ghosh)

0.173447

Dipole Polarity

Accepted

50

Uncertainty

2

C6 GB

509

Lattice

Constant Internal Default Radius

3.46

Strucutre

HEX

Angles

π/2, π/2, 2 π/3

Electron & Quantum

Oxidation States

−5,−2,−1,1,2,3

Electron Configuration

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p1

Quantum Number

2b1/a

Electron Configuration Semantic

[Rook] 4f14 5d10 6s2 6p1

Shells-0

2

Shells-1

8

Shells-2

18

Shells-3

32

Shells-4

18

Shells-5

3

Ionization Energies-0

589.4

Ionization Energies-1

1971

Ionization Energies-2

2878

List of Compounds

1-10 of 48 compounds

FormulaNames
Tlthallium

thallium metal

Tl3As

thallium(I)arsenide

arsenic; thallium

TlBr

thallium(I) bromide

bromothallium

thallium bromide

thallium monobromide

thallous bromide

TlCl

thallium chloride

chlorothallium

thallium(1+) chloride

thallium(I) chloride

thallous chloride

Cl3Tl

thallium(III) chloride

TlF

thallium(I) fluoride

fluorothallium

thallium fluoride

thallium monofluoride

thallous fluoride

TlF3

thallium(III)fluoride

trifluorothallane

TlI

thallium(I)iodide

iodothallium

thallium iodide

thallium monoiodide

thallous iodide

OTl2

thallium(I) oxide

Tl2O3

thallium(III)oxide

keto-ketothallanyloxy-thallane

oxo-oxothallanyloxythallane


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